(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
CAS: 870987-63-6
Molecular Formula: F6P-
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate - Names and Identifiers
| Name | (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate |
| Synonyms | (4,4'-Di-t-butyL Ir[dF(CF3)ppy]2(dtbbpy)PF6 [Ir(dtbbpy)[dF(CF3)ppy]2]PF6 4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+) 4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate |
| CAS | 870987-63-6 |
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate - Physico-chemical Properties
| Molecular Formula | F6P- |
| Molar Mass | 144.9641802 |
| Melting Point | >300 °C |
| Solubility | Chloroform (Slightly) |
| Appearance | crystal |
| Color | yellow |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | No |
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate - Introduction
(4,4 '-Bis (1,1-dimethylethyl)-2,2'-bipyridine N1,N1 '] bis [3,5-difluoro -2- [5-(trifluoromethyl)-2-pyridyl N] phenyl-C] iridium (III) hexafluorophosphate, abbreviated as Ir(ppy)2(dtbbpy)PF6, is a metal-organic complex.
Nature:
1. Appearance: Ir(ppy)2(dtbbpy)PF6 is a light yellow to yellow powder solid.
2. Structure: It consists of an iridium ion, two ligands (ppy and dtbbpy) and a hexafluorophosphate ion.
3. Melting point: Its melting point is about 150-200°C.
4. insoluble: in common organic solvents such as ether, toluene and acetone with good solubility.
Use:
1. Optoelectronic devices: Ir(ppy)2(dtbbpy)PF6 is a light-emitting material that can be used as a light-emitting layer or light-absorbing material in organic light-emitting diodes (OLEDs) and organic photovoltaic devices (OPVs).
2. Catalyst: It can also be used as a photocatalyst for photocatalytic reactions.
3. Organic synthesis: Ir(ppy)2(dtbbpy)PF6 can be used as a catalyst in organic synthesis, for catalytic oxidation, reduction, carbonylation reactions.
Preparation Method:
the preparation of Ir(ppy)2(dtbbpy)PF6 is generally synthesized by metal coordination chemical method, the specific steps are as follows:
1. An appropriate amount of IrCl3.xH2O reacts with dtbbpy in an appropriate solvent to generate Ir(dtbbpy)Cl2.
2. Ir(dtbbpy)Cl2 is reacted with ppy under basic conditions to produce Ir(ppy)2(dtbbpy)Cl.
3. Finally, Ir(ppy)2(dtbbpy)Cl is reacted with hexafluorophosphate to obtain the final product Ir(ppy)2(dtbbpy)PF6.
Safety Information:
Regarding the safety of Ir(ppy)2(dtbbpy)PF6, the relevant toxicity data and safety information are currently limited. Therefore, it is necessary to follow the corresponding safety procedures and use personal protective measures to avoid contact with skin, eyes and mouth. At the same time, the relevant chemical safety data sheets should be carefully read before use, and relevant regulations and operating guidelines should be followed.
Nature:
1. Appearance: Ir(ppy)2(dtbbpy)PF6 is a light yellow to yellow powder solid.
2. Structure: It consists of an iridium ion, two ligands (ppy and dtbbpy) and a hexafluorophosphate ion.
3. Melting point: Its melting point is about 150-200°C.
4. insoluble: in common organic solvents such as ether, toluene and acetone with good solubility.
Use:
1. Optoelectronic devices: Ir(ppy)2(dtbbpy)PF6 is a light-emitting material that can be used as a light-emitting layer or light-absorbing material in organic light-emitting diodes (OLEDs) and organic photovoltaic devices (OPVs).
2. Catalyst: It can also be used as a photocatalyst for photocatalytic reactions.
3. Organic synthesis: Ir(ppy)2(dtbbpy)PF6 can be used as a catalyst in organic synthesis, for catalytic oxidation, reduction, carbonylation reactions.
Preparation Method:
the preparation of Ir(ppy)2(dtbbpy)PF6 is generally synthesized by metal coordination chemical method, the specific steps are as follows:
1. An appropriate amount of IrCl3.xH2O reacts with dtbbpy in an appropriate solvent to generate Ir(dtbbpy)Cl2.
2. Ir(dtbbpy)Cl2 is reacted with ppy under basic conditions to produce Ir(ppy)2(dtbbpy)Cl.
3. Finally, Ir(ppy)2(dtbbpy)Cl is reacted with hexafluorophosphate to obtain the final product Ir(ppy)2(dtbbpy)PF6.
Safety Information:
Regarding the safety of Ir(ppy)2(dtbbpy)PF6, the relevant toxicity data and safety information are currently limited. Therefore, it is necessary to follow the corresponding safety procedures and use personal protective measures to avoid contact with skin, eyes and mouth. At the same time, the relevant chemical safety data sheets should be carefully read before use, and relevant regulations and operating guidelines should be followed.
Last Update：2024-04-09 21:54:55
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